Mathematical Analysis
Minima of Conduction Band Valleys in [eV] at 300K: AlxGa1-xAs [ref:1]
Eg(x) =
1.424 + 1.247x
(0 < x < 0.45)
1.424 + 1.247 + 1.147(x-0.45)2 (0.45
< x < 1.0)
EL(x) = 1.708 + 0.642x
EX(x) = 1.900 + 0.125 + 0.143x2
E(k) Diagram : Effective Masses for AlxGa1-xAs [ref:1, 2]
A) Conduction Band Valleys
Eg(k) = h2k2/2mg*
where,
mg*/m0 = 0.067 + 0.083x
(for Density of States); 0.067 + 0.083x (for Conductivity)
kg = 2p/a
(0, 0, 0)
EL(k) = h2(k-kL)2/2mL*
where,
mL*/m0 = 0.56 + 0.1x (for DOS); 0.11 + 0.03x (for
Conductivity)
kL = 2p/a (1/2, 1/2, 1/2)
EX(k) = h2(k-kX)2/2mX*
where,
mX*/m0 = 0.85 - 0.14x (for DOS); 0.32 - 0.06x (for
Conductivity)
kX = 2p/a (0, 0, 1-D)
B) Valence Band Valleys
Ehh(k) = h2k2/2mhh*
where,
mhh*/m0 = 0.62 + 0.14x
Elh(k) = h2k2/2mlh*
where,
mlh*/m0 = 0.087 + 0.063x
Eso(k) = h2k2/2mso*
- Do where,
mso*/m0 = 0.15 + 0.09x
Do = 0.34 - 0.04x
The Density of States effective mass for valence
band, mvb, is found from
mvb = (mlh*3/2 + mhh*3/2)2/3
Eso(k) is the split-off band and
does not contribute to the DOS.